July 31, 2017
HBr–DMPU: The First Aprotic Organic Solution of Hydrogen Bromide
Li, Z., Ebule, R., Kostyo, J., Hammond, G. B., & Xu, B. (2017). “HBr–DMPU: The First Aprotic Organic Solution of Hydrogen Bromide” Chemistry–A European Journal, 23(52), 12739–12743.
Abstract: HBr and DMPU (1,3-dimethyl-3,4,5,6-tetrahydro-2-pyrimidinone) form a room-temperature-stable complex that provides a mild, effective, and selective hydrobrominating reagent toward alkynes, alkenes, and allenes. HBr–DMPU could also replace other halogenating reagents in the halo-Prins reaction, ether cleavage, and deoxy-bromination reactions.